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Prof. em. Dr. Adalbert Maercker

  • Carbanions - Chemistry
  • Alkali metal organic compounds
  • Polylithiated compounds

1. the reaction of aromatic spiro-phosphoranes
G. Wittig, A. Maercker
Chem. Ber. 97 (1964) 747-768.

2 The Wittig Reaction
A. Maercker
Organic Reactions 14, 270-490
John Wiley and Sons, New York 1965.

3 Influence of Vinyl and Phenyl Substituents on the Interconversion of Allylcarbinyl-Type Grignard Reagents
M. E. H. Howden, A. Maercker, J. Burdon, J. D. Roberts
J. Amer. Chem. Soc. 88 (1966) 1732-1742.

4 Stabilized Cyclopropylcarbinyl Anions. A Retro Cyclopropylcarbinyl- Allylcarbinyl Rearrangement
A. Maercker, J. D. Roberts
J. Amer. Chem. Soc. 88 (1966) 1742-1759.

5. nucleophilic displacement of phenyl groups in phosphines, arsines, stibines and bismutines by aryllithium compounds
G. Wittig, A. Maercker
J. Organomet. Chem. 8 (1967) 491-494.

6. cyclopropylmethylene-triphenylphosporane
A. Maercker
Angew. Chem. 79 (1967) 576-577; Angew. Chem. Int. ed. Engl. 6 (1967) 557-558.

7. on the mutual rearrangement of cyclopropylmethyl and allylmethyl anions
A. Maercker
Habilitation thesis, University of Erlangen-Nuremberg, 1968.

8. ether cleavages with magnesium: a direct approach to allylmagnesium phenolates
A. Maercker
J. Organomet. Chem. 18 (1969) 249-262

9. on the kinetics of the rearrangement of allyl carbinyl anions (3-butenide ions)
A. Maercker, K. Weber
Angew. Chem. 81 (1969) 931; Angew. Chem. Int. ed. Engl. 8 (1969) 912.

10. on the cleavage of cyclopropylcarbinyl phenyl ether with alkali metals
A. Maercker
Liebigs Ann. Chem. 730 (1969) 91-99.

11. on the addition of alkali metals to 1,1-diphenyl-2-cyclopropyl ethylene
A. Maercker
Liebigs Ann. Chem. 732 (1970) 151-164.

12. ring constriction in the rearrangement of 3-cyclohexenyl-Grignard compounds
A. Maercker, R. Geuß
Angew. Chem. 82 (1970) 938-939; Angew. Chem. Int. ed. Engl. 9 (1970) 909.

13. inversion of secondary cyclic Grignard compounds
A. Maercker, R. Geuß
Angew. Chem. 83 (1971) 288-289; Angew. Chem. Int. ed. Engl. 10 (1971) 270-271.

14. secondary reactions in the decomposition of diethyl ether and tetrahydrofuran by n-butyllithium
A. Maercker, W. Theysohn
Liebigs Ann. Chem. 747 (1971) 70-83.

15. experiments on the rearrangement of allylcarbinyl into cyclobutyl anions
A. Maercker, K. Weber
Liebigs Ann. Chem. 756 (1972) 20-32.

16. precipitation of magnesium during the decomposition of an allylcarbinyl primary compound in diethyl ether
A. Maercker, K. Weber
Liebigs Ann. Chem. 756 (1972) 33-42.

17. on the kinetics of the rearrangement of allylcarbinyl anions. Isotope effects on the equilibrium position between - and -deuterated allylcarbinyl primary compounds
A. Maercker, K. Weber
Liebigs Ann. Chem. 756 (1972) 43-78.

18. experiments on the rearrangement of 2-cyclopropyl ethyl anions
A. Maercker, W. Theysohn
Liebigs Ann. Chem. 759 (1972) 132-157.

19. rearrangement of 3-butenyl green standard compounds: anionic or radical?
A. Maercker, W. Streit
Angew. Chem. 84 (1972) 531-533; Angew. Chem. Int. ed. Engl. 11 (1972) 542-543.

20. rearrangement of cyclic allyl carbinyl anions: Ring constriction due to stability differences between primary and secondary Grignard compounds
A. Maercker, R. Geuß
Chem. Ber. 106 (1973) 773-797.

21 On the mechanism of the cleavage of diethyl ether with alkyl lithium compounds: Different decomposition mechanisms for - and -deuterated diethyl ether
A. Maercker, W. Demuth
Angew. Chem. 85 (1973) 90-92; Angew. Chem. Int. ed. Engl. 12 (1973) 75-76.

22. influences of - and -alkyl groups on the rearrangement of 3-butenyl primary compounds: A stable, primary cyclopropylmethyl anion
A. Maercker, P. Güthlein, H. Wittmayr
Angew. Chem. 85 (1973) 823-824; Angew. Chem. Int. ed. Engl. 12 (1973) 774-775.

23. NMR spectroscopic studies on organolithium and magnesium compounds
A. Maercker
Chem.-Ztg. 97 (1973) 361-368.

24. intramolecular 1,3- and 1,4-proton shift as a secondary reaction in the decomposition of tetrahydrofuran by benzyl- and phenyllithium
A. Maercker, J. Troesch
J. Organomet. Chem. 102 (1975) C1-C3.

25. ether cleavages with magnesium II. allylmagnesium naphtholates from allyl naphthyl ethers
A. Maercker, H.-J. Jaroschek
J. Organomet. Chem. 108 (1976) 145-151.

26. ether cleavages with magnesium III. criteria for the cleavability of thioethers
A. Maercker, H.-J. Jaroschek
J. Organomet. Chem. 116 (1976) 21-37.

27. on the mechanism of the 1,2-vinyl shift in the rearrangement of 3-butenyl primary compounds: Arguments against a radical progression
A. Maercker, W. Streit
Chem. Ber. 109 (1976) 2064-2089.

28. evidence of ,-elimination and Wittig rearrangement next to - and -elimination in the cleavage of dialkyl ethers with alkyllithium compounds
A. Maercker, W. Demuth
Liebigs Ann. Chem. 1977, 1909-1937.

29 Side and Consecutive Reactions in Metallation of Alkyl Phenyl Ethers: I. The Reaction of Phenetols with Ethyllithium
A. Maercker, R. W. Stumpe
Tetrahedron Lett. 1979, 3843-3846.

30. carbanion rearrangements by intramolecular 1,-proton shift,
II. On the reaction mode of 3-, 4- and 5-lithioalkyl-trimethylsilanes
A. Maercker, M. Eckers, M. Passlack
J. Organomet. Chem. 186 (1980) 193-205.

31st Magnesium; Annual Survey Covering the Year 1978
A. Maercker
J. Organomet. Chem. 211 (1981) 1-175.

32. carbanion rearrangements by intramolecular 1,-proton shift, III.
On the reaction mode of 2-, 3-, 4- and 5-phenylalkyllithium compounds
A. Maercker, M. Passlack
Chem. Ber. 115 (1982) 540-577.

33 High-field NMR spin decoupling in organo-mercury compounds
R. Benn, H. Günther, A. Maercker, V. Menger, P. Schmitt
Angew. Chem. 94 (1982) 314+317; Angew. Chem. Int. ed. Engl. 21 (1982) 295-296.

34. carbanion rearrangements by intramolecular 1, -proton displacement, IV.
On the reaction mode of ,-diphenylalkyllithium compounds: Evidence for intramolecular remetallation by crossover experiments with isotopically labeled starting material
A. Maercker, M. Passlack
Chem. Ber. 116 (1983) 710-723.

35. on the mode of formation of 1-phenylpropyllithium from benzyllithium and ethylene in tetrahydrofuran
A. Maercker, R. Stötzel
J. Organomet. Chem. 254 (1983) 1-12.

36 Unexpected ring opening of benzocyclobutenes upon reaction with lithium in tetrahydrofuran
A. Maercker, W. Berkulin, P. Schiess
Angew. Chem. 95 (1983) 248-251; Angew. Chem. Int. ed. Engl. 22 (1983) 246-247.

37. polylithium organic compounds, 1st communication. 1,1-Dilithioethane
A. Maercker, M. Theis, A. J. Kos, P. von R. Schleyer
Angew. Chem. 95 (1983) 755-757; Angew. Chem. Int. ed. Engl. 22 (1983) 733-734.

38. ring opening and metallation of 1,1-dimethyl-2-phenyl-silacyclopentane under the influence of methyl lithium in tetrahydrofuran
A. Maercker, R. Stötzel
J. Organomet. Chem. 269 (1984) C4O-C46.

39. on the interchangeability of methyl and phenyl groups on the silicon of silacyclopentane when exposed to alkyl and aryllithium compounds in diethyl ether or tetrahydrofuran
A. Maercker, R. Stötzel
J. Organomet. Chem. 273 (1984) C57-C63.

40. dimerization of benzocyclobutene to 1-ethyl-9,10-dihydrophenanthrene under the influence of sodium-potassium alloy in tetrahydrofuran
A. Maercker, W. Berkulin, P. Schiess
Tetrahedron Lett. 25 (1984) 1701-1702.

41. preparation and crystal structure of 3-(lithiomethyl)-1,1,2,2-tetramethylcyclopropane, a stable cyclopropylmethyllithium compound
A. Maercker, M. Bsata, W. Buchmeier, B. Engelen
Chem. Ber. 117 (1984) 2547-2554.

42. polylithium organic compounds, 2nd communication.
Dilithiomethylene-cyclohexane - a stable 1,1-dilithioalkene
A. Maercker, R. Dujardin
Angew. Chem. 96 (1984) 222; Angew. Chem. Int. ed. Engl. 23 (1984) 224.

43. polylithium organic compounds, 3rd communication.
Tetralithiomethane
A. Maercker, M. Theis
Angew. Chem. 96 (1984) 990-991; Angew. Chem. Int. ed. Engl. 23 (1984) 995-996.

44 A Technique for Introducing Air-sensitive Compounds into a Mass Spectrometer and its Application to the Study of Alkyllithium Compounds
M. Guilhaus, A. G. Brenton, J. H. Beynon, M. Theis, A. Maercker
Org. Mass. Spectrom. 2O (1985) 592-594.

45. polylithium organic compounds, 4th communication.
2,3-Dilithio-1,3-butadiene by addition of lithium to butatrienes
A. Maercker, R. Dujardin
Angew. Chem. 97 (1985) 612-613; Angew. Chem. Int. ed. Engl. 24 (1985) 571-572.

46. disclosure DE 362O244 A 1;
Inventors: A. Maercker, R. Dujardin

47. polylithium organic compounds, 5th communication.
Vicinal dilithioalkenes by addition of lithium to simple cyclic and acyclic alkynes
A. Maercker, T. Graule, U. Girreser
Angew. Chem. 98 (1986) 174-176; Angew. Chem. Int. ed. Engl. 25 (1986) 167-168.

48. (Dilithiomethylene)cyclohexanes
A. Maercker, R. Dujardin
Organometallic Syntheses 3 (1986) 356-358.

49. tetralithiomethanes
A. Maercker, M. Theis
Organometallic Syntheses 3 (1986) 378-380.

50. cinnamylmagnesium phenoxide
A. Maercker
Organometallic Syntheses 3 (1986) 398-4OO.

51. 6Li, 6Li-COSY - A New Tool for Structure Determinations of Lithium Organic Compounds in Solution
H. Günther, D. Moskau, R. Dujardin, A. Maercker
Tetrahedron Lett. 27 (1986) 2251-2254.

52 Some Aspects of the Chemistry of Polylithiated Aliphatic Hydrocarbons
A. Maercker, M. Theis
Topics in Current Chemistry 138 (1987) 1-61.

53 Experimental Search for the Stevens Rearrangement of Phosphorus Ylids via Ring-Chain Equilibria
A. Maercker, B. Bsata, R. Jung
Main Group Metal Chemistry 1O (1987) 11-17.

54. carbanion rearrangements by intramolecular 1,-proton shift, V. Carbanion rearrangements of -phenyl--(trimethylsilyl)alkyllithium compounds: Intramolecular reactions of benzyltrimethylsilanes with a carbon-lithium bond
A. Maercker, R. Stötzel
Chem. Ber. 120 (1987) 1695-1706.

55 Double Quantum Based 6Li, 13C NMR Correlation Spectroscopy
D. Moskau, F. Brauers, H. Günther, A. Maercker
J. Am. Chem. Soc. 109 (1987) 5532-5534.

56. ether cleavages with organoalkali metal compounds and alkali metals
A. Maercker
Angew. Chem. 99 (1987) 1002-1019; Angew. Chem. Int. ed. Engl. 26 (1987) 972-989.

57. polylithium organic compounds, 6th communication.
cis- and trans-1,2-dilithioethylene
A. Maercker, T. Graule, W. Demuth
Angew. Chem. 99 (1987) 1075-1076; Angew. Chem. Int. ed. Engl. 26 (1987) 1032-1034.

58. polylithium organic compounds, 7th communication.
Dilithioacetylene instead of 1,2-dilithioethane in the reaction of ethylene with lithium, a correction
A. Maercker, B. Grebe
J. Organomet. Chem. 334 (1987) C21-C23.

59. polylithium organic compounds, 8th communication.
A tetramethylene-1,4-distannacyclohexane from 3,4-dilithio-2,5-dimethyl-2,4-hexadiene and dichlorodimethylstannane, the first dimetalla[6]radial
A. Maercker, F. Brauers, W. Brieden, M. Jung, H. D. Lutz
Angew. Chem. 100 (1988) 413-414; Angew. Chem. Int. ed. Engl. 27 (1988) 404-405.

60. cis-1,2-Dilithiocyclooctene
A. Maercker, T. Graule, U. Girreser
Organometallic Syntheses 4 (1988) 366-367.

61. 3,4-Dilithio-2,5-dimethyl-2,4-hexadiene
A. Maercker, R. Dujardin, F. Brauers
Organometallic Syntheses 4 (1988) 362-365.

62. polylithium organic compounds, 9th communication.
Stable open-chain 1,3-dilithium compounds by the reaction of methylenecyclopropanes with lithium powder: 2,4-dilithio-1-butenes
A. Maercker, K.-D. Klein
Angew. Chem. 101 (1989) 63-64; Angew. Chem. Int. ed. Engl. 28 (1989) 83-84.

63. polylithium organic compounds, 10th communication.
Tetramethylene-1,4-diboracyclohexanes from 3,4-dilithio-2,5-dimethyl-2,4-hexadiene. The first hetero[6]radial in the armchair conformation
A. Maercker, W. Brieden, Th. Schmidt, H.D. Lutz
Angew. Chem. 101 (1989) 477-479; Angew. Chem. Int. ed. Engl. 28 (1989) 477-478.

64. polylithium organic compounds, 11th communication.
1,4-Disila[6]radialenes in two stable conformational isomeric forms, twist and armchair conformation, which do not convert into each other at room temperature
A. Maercker, F. Brauers, W. Brieden, B. Engelen
J.Organomet.Chem. 377 (1989) C45-C51.

65. experiments on the rearrangement of cyclobutyl into 3-butenyl anions:
Endocyclic ring opening in the reaction of (3,3-diphenyl-1-vinylcyclobutyl)methyl ether with alkali metals - anionic or radical?
A. Maercker, W. Berkulin
Chem. Ber. 123 (1990) 185-192.

66. polylithium organic compounds, 12th communication.
Reductive cleavage of a cyclopropane bond in the reaction of cyclopropylacetylenes with elemental lithium - a cis-1,2-dilithioalkene as an intermediate
A. Maercker, U. Girreser
Angew. Chem. 102 (1990) 718-719; Angew. Chem. Int. ed. Engl. 29 (1990) 667-669.

67 On the Mechanism of Bibenzyl Formation by Deoxidation/Reduction of Aromatic Species with Lithium 4,4'-Di-t-butylbiphenyl Radical Anion - A Correction
A. Maercker, U. Girreser
Tetrahedron Lett. 31 (1990) 7595-7596.

68 Influence of Solvent and Cation on the Properties of Oxygen-containing Organic Anions. Part 4. Mechanism and Reactivity of Tetraaryloxirane Cleavage with Alkali Metals.
M.L.T.M.B. Franco, B.J. Herold and A. Maercker
J. Chem. Soc. Perkin Trans. 2 1991, 119-129.

69. polylithiumorganic compounds, XIII.
"Phospha[3]radialenes" - Reactive Intermediates in the Synthesis of "Phospha[6]radialenes"
A. Maercker and W. Brieden
Chem. Ber. 124 (1991) 933-938.

70. polylithium organic compounds, XIV.
The reported 1,1-dilithio-2-isopropoxy-2-phenylethene does not exist - a Quasi Dianion Complex is formed instead
A. Maercker and B. Bös
Main Group Metal Chem. 14 (1991) 67-71.

71. polylithium organic compounds XV.
Reductive cleavage of a cyclobutane bond and rearrangement of the primary 1,4-dilithio compound under 1,7-proton shift in the reaction of diphenylmethylenecyclobutane with elemental lithium
A. Maercker and K.-D. Klein
J. Organomet. Chem. 401 (1991) C1-C4.

72. polylithium organic compounds, 16th communication.
1,4-Disila[6]radialenes: activation parameters of the Sessel-Twist inversion and analytical enantiomer separation of the twist conformers
A. Maercker, W. Brieden, F. Kastner and A. Mannschreck
Chem. Ber. 124 (1991) 2033-2036.

73. polylithium organic compounds, 17th communication.
Cleavage of 1,1'-bicyclopropylidene (butterfly olefin) with lithium powder to 1,6-dilithio-3-hexine via (1,3-dilithiopropylidene)cyclopropane as an isolable intermediate
A. Maercker and K.-D. Klein
J. Organomet. Chem. 410 (1991) C35-C38.

74 Studies on the enantio- and diastereoselective metallation of prochiral sulfoxides with (+)-menthyllithium
A. Maercker, R. Schuhmacher, W. Buchmeier and H.D. Lutz
Chem. Ber. 124 (1991) 2489-2498.

75 Homonuclear Scalar 6Li6Li Spin-Spin Coupling: First Direct Observation and Detection via the 6Li, 6Li INADEQUATE Experiment
O. Eppers, H. Günther, K.-D. Klein and A. Maercker
Magn. Reson. Chem. 29 (1991) 1065-1067.

76. perlithiated and hyperlithiated methane
A. Maercker
Angew. Chem. 104 (1992) 598-599; Angew. Chem. Int. ed. Engl. 31 (1992) 584-585.

77. polylithium organic compounds, 18th communication.
Control of the reaction of n-butyllithium with benzo[b]tellurol by the solvent - optional metallation or tellurium-lithium exchange to an interesting lithiostyryllithium
A. Maercker, H. Bodenstedt and L. Brandsma
Angew. Chem. 104 (1992) 1387-1388; Angew. Chem. Int. ed. Engl. 31 (1992) 1339-1341.

78. selectivity between deprotonation and attack on tellurium in the reaction of 1,4-thiatellurins with strongly basic reagents
H.J.M. Schoufs, A. Maercker and L. Brandsma
J. Organomet. Chem. 441 (1992) 1-6.

79. 1,4-Disila[6]radialenes in two stable conformational isomeric forms - twist and armchair conformation - which do not convert into each other at room temperature
A. Maercker u. W. Brieden
in "Kolloquium über Organosilicumchemie 1991"
Referateband (Hrsg. K. Rühlmann) Dresden 1992, 99-103

80. successful X-ray structure analysis of an alkylidene carbenoid - a milestone in carbenoid research
A. Maercker
Angew. Chem. 105 (1993) 1072-1074; Angew. Chem. Int. ed. Engl. 32 (1993) 1023-1025.

81 Two-Dimensional 6Li, 1H-NMR Shift Correlation by Multiple Quantum Spectroscopy and Polarization Transfer: New Tools for Structural Research in the Field of Organolithium Compounds
H.-E. Mons, H. Günther, A. Maercker
Chem. Ber. 126 (1993) 2747-2751.

82. di- and polycarbanions
A. Maercker
in "Methods of Organic Chemistry (Houben-Weyl)" Vol. E19d
(ed. M. Hanack) Thieme, Stuttgart 1993, 448-566.

83 The Reaction of Vinylsilanes with Lithium Metal
A. Maercker and K. Reider
in "Organosilicon Chemistry, From Molecules to Materials"
(ed.: N. Auner, J. Weis) VCH-Verlagsgesellschaft,
Weinheim 1994, 123-124.

84. polylithiumorganic Compounds - 19.
Regioselective Carbon-Carbon -Bond Scission followed by a 1,6-Proton Shift upon the Reductive Metalation of Benzylidenecyclopropane Derivatives with Lithium Metal
A. Maercker and V. E. E. Daub
Tetrahedron 50 (1994) 2439-2458.

85. Polylithiumorganic Compounds - 20.
Stereoselective Synthesis of Vicinal Dilithioalkenes by Addition of Lithium Metal to Carbon-Carbon Triple Bonds
A. Maercker and U. Girreser
Tetrahedron 50 (1994) 8019-8034.

86. 2,2'-Dilithio-1,1'-bicyclooctenyl: Synthesis and Reactions with Electrophiles
A. Maercker and U. Girreser
Tetrahedron Lett. 35 (1994) 9197-9198.

87. polylithiumorganic compounds - 21.
On the Deprotonation of 1- and 3-Phenylpropyne as well as Phenylallene with Butyllithium. A Reinvestigation: Three Different Monoanions but one and the same Dianion.
A. Maercker and J. Fischenich
Tetrahedron 51 (1995) 10209-10218.

88 Preparation and Reactions of Polylithiumorganic Compounds
A. Maercker
in "Lithium Chemistry: A Theoretical and Experimental Overview"
(ed. A.-M. Sapse and P. v. R. Schleyer)
Wiley, New York 1995, pp. 477-577.

89 Solution-Structure and Aggregation Behavoir of Two Dilithiostyrene Derivatives
H. Günther, O. Eppers, H. Hausmann, D. Hüls, H.-E. Mons, K.-D. Klein, and
A. Maercker
Helvetica Chimica Acta 78 (1995) 1913-1932.

90. polylithium organic compounds, 22nd communication.
Synthesis of the first titana[3]radialene and its ring extension to a titanacyclopentene
A. Maercker and A. Groos
Angew. Chem. 108 (1996) 216-218; Angew. Chem. Int. ed. Engl. 35 (1996) 210-212.

91. polylithium organic compounds - 23.
3,4-Dilithio-1,2-butadienes by Addition of Lithium Metal to 1,4-Unsymmetrically Substituted Butatrienes
A. Maecker, H. Wunderlich, and U. Girreser
Tetrahedron 52 (1996) 6149-6172.

92 Novel Pathways in the Reaction of Vinylsilanes with Lithium Metal
A. Maercker, K. Reider, and U. Girreser
in "Organosilicon Chemistry, From Molecules to Materials" Vol. 3 (ed. N. Auner, J. Weis) VCH-Verlagsgesellschaft, Weinheim 1997, pp. 195-205.

93 Polylithiumorganic Compounds - 24 The Reaction of Substituted Vinylsilanes with Lithium Meltal
A. Maercker, K. Reider, and U. Girreser
Eur. J. Org. Chem. 1998, 1455-1465.

94 Mechanism of the reduction of diphenylacetylene with metallic lithium
A. Maercker, M. Kemmer, H. C. Wang, D.-H. Dong and M. Szwarc
Angew. Chem. 110 (1998) 2216-2218; Angew. Chem. Int. ed. 37 (1998) 2136-2138.

95. polylithium organic compounds - 25. controlled rearrangement of 2,3-dilithio-1,3-butadienes to 2,5-dilithio-1,3-butadienes: synthesis of 2-isopropylidene-2,5-dihydrosilols
A. Maercker, H. Wunderlich, and U. Girreser
Eur. J. Org. Chem. 1998, 793-798.

96 Polylithiumorganic Compounds - 26 Formation and rearrangement of gem-dilithiodiphenylethene
A. Maercker, B. Bös, M. T. Hajgholipour
J. Organomet. Chem. 566 (1998) 143-149.

97 Scission of C-C s-Bonds via Electron Transfer Processes
A. Maercker, V. E. E. Daub, A. Deskowski, K.-D. Klein, K. S. Oeffner, and H. Schutz
Macromol. Symp. 134 (1998) 83-93.

98. new facts concerning the reaction of K-, K+(15-crown-5)2 with phenyl glycidyl ether: unexpected formation of potassium cyclopropoxide
Z. Grobelny, A. Stolarzewicz, A. Maercker, W. Demuth
J.Organomet. Chem. 590 (1999) 153-157.

99. Unexpected Cleavage of Crown Ether in the Reaction of Methyloxirane with K-, K+(15-crown-5)2
Z. Grobelny, A. Stolarzewicz, M. Czaja, W. Demuth, and A. Maercker
J. Org. Chem. 64 (1999) 8990-8994.

100. decomposition of the crown ether ring in the reaction of K-, K+(15-crown-5)2 with oxetane
Z. Grobelny, A. Stolarzewicz, A. Maercker
J. Organomet. Chem. 604 (2000) 283-286.

101 Polylithium Organic Compounds. Part 27: C,C-Bond Forming Reactions of 3,4-Dilithio-2,5-dimethyl-2,4-hexadiene
A. Maercker, J. van de Flierdt and U. Girreser
Tetrahedron 56 (2000) 3373-3383.

102 Self-decomposition of K-, K+(15-crown-5)2 tetrahydrofuran solution via organometallic intermediates
Z. Grobelny, A. Stolarzewicz, A. Maercker
J. Organomet. Chem. 628 (2001) 65-70.

103 Polylithiumorganic compounds. Part 28: The reaction of allene and alkyl substituted allenes with lithium metal
A. Maercker, A. Tatai, B. Grebe, U. Girreser
J. Organomet. Chem. 642 (2002) 1-8.

104 Preparation and Decomposition of Potassium Alkalide - Lipophilic Crown Ether Complexes in Tetrahydrofuran
Z. Grobelny, A. Stolarzewicz, B. Morejko-Buz, R. A. Bartsch, K. Yamato, F. A. Fernandez, A. Maercker
J. Org. Chem. 67 (2002) 7807-7812.

105. selective cleavage of the linear ether bond in benzyl glycidyl ether and triphenylmethyl glycidyl ether by potassium alkalide as two-electron-transfer reagent
Z. Grobelny, A. Stolarzewicz, B. Morejko-Buz, A. Maercker
J. Organomet. Chem. 660 (2002) 6-13.

106. cleavage of different ether bonds in butyl glycidyl ether and allyl glycidyl ether by K-, K+(15-crown-5)2
Z. Grobelny, A. Stolarzewicz, A. Maercker, S. Krompiec, T. Bieg
J. Organomet. Chem. 660 (2002) 133-138.

107 Study on the initiation step of 2-(9-carbazolyl)ethyl glycidyl ether polymerization by K-, K+(15-crown-5)2
Z. Grobelny, A. Stolarzewicz, B. Morejko-Buz, G. Buika, J. V. Grazulevicius, A. Maercker
Eur. Polym. J. 38 (2002) 2359-2363.

108. regioselectivity of the ring opening in the reaction of phenyloxirane, (phenylmethyl)oxirane and (2-phenylethyl)oxirane with K-, K-, K+(15-crown-5)2
Z. Grobelny, A. Stolarzewicz, B. Morejko-Buz, A. Maercker, S.Kropiec, T.Bieg
J. Organomet. Chem. 672 (2003) 43-51.

109. polylithiumorganic compounds. Part 29: C,C Bond cleavage of phenyl substituted and strained carbocycles using lithium metal
A. Maercker, K. S. Oeffner, U. Girreser
Tetrahedron 60 (2004) 8245-8256.

110 Electron-transfer reduction of selected alcohols with alkalide K-, K+(15-crown-5)2 via organometallic intermediates
Z. Grobelny, A. Stolarzewicz, A. Maercker, S. Krompiec, J. Kasperczyk, J. Rzepa, H. Frey
J. Organomet. Chem. 689 (2004) 2361-2367.

111. decomposition of vinyl ethers by alkalide K-, K+(15-crown-5)2 via organopotassium intermediates
Z. Grobelny, A. Stolarzewicz, A. Maercker, S. Krompiec, J. Kasperczyk, J. Rzepa
J. Organomet. Chem. 689 (2004) 1580-1585.

112. study on the initiation step of vinyloxirane and 3-butenyloxirane polymerization by alkalide K-, K+(15-crown-5)2
Z. Grobelny, A. Stolarzewicz, B. Morejko-Buz, A. Maercker
European Polymer Journal 40 (2004) 409-414.